A ductile solid electrolyte interphase for solid
Kalnaus, S., Dudney, N. J., Westover, A. S., Herbert, E. & Hackney, S. Solid–state batteries: the critical role of mechanics. Science 381, eabg5998 (2023).
Google Scholar
Alexander, G. V., Shi, C., O’Neill, J. & Wachsman, E. D. Extreme lithium-metal cycling enabled by a mixed ion- and electron-conducting garnet three-dimensional architecture. Nat. Mater. 22, 1136–1143 (2023).
Google Scholar
Yang, C. et al. Copper-coordinated cellulose ion conductors for solid-state batteries. Nature 598, 590–596 (2021).
Google Scholar
Liu, J. et al. Pathways for practical high-energy long-cycling lithium metal batteries. Nat. Energy 4, 180–186 (2019).
Google Scholar
Wan, H., Wang, Z., Zhang, W., He, X. & Wang, C. Interface design for all-solid-state lithium batteries. Nature 623, 739–744 (2023).
Google Scholar
Hitz, G. T. et al. High-rate lithium cycling in a scalable trilayer Li-garnet-electrolyte architecture. Mater. Today 22, 50–57 (2019).
Google Scholar
Wan, J. et al. Ultrathin, flexible, solid polymer composite electrolyte enabled with aligned nanoporous host for lithium batteries. Nat. Nanotechnol. 14, 705–711 (2019).
Google Scholar
Zhang, W. et al. Single-phase local-high-concentration solid polymer electrolytes for lithium-metal batteries. Nat. Energy 9, 386–400 (2024).
Google Scholar
Yang, K. et al. Determining the role of ion transport throughput in solid-state lithium batteries. Angew. Chem. Int. Ed. 135, e202302586 (2023).
Google Scholar
Albertus, P., Babinec, S., Litzelman, S. & Newman, A. Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries. Nat. Energy 3, 16–21 (2017).
Google Scholar
Yang, K. et al. Weak-interaction environment in a composite electrolyte enabling ultralong-cycling high-voltage solid-state lithium batteries. J. Am. Chem. Soc. 16, 11371–11381 (2024).
Wan, H. et al. Interface design for high-performance all-solid-state lithium batteries. Adv. Energy Mater. 14, 2303046 (2023).
Google Scholar
Xu, R. et al. Artificial soft–rigid protective layer for dendrite-free lithium metal anode. Adv. Funct. Mater. 28, 1705838 (2018).
Google Scholar
Vitos, L., Korzhavyi, P. A. & Johansson, B. Elastic property maps of austenitic stainless steels. Phys. Rev. Lett. 88, 155501 (2002).
Google Scholar
Pugh, S. F. Relations between the elastic moduli and the plastic properties of polycrystalline pure metals. Lond. Edinb. Dubl. Philos. Mag. 45, 823–843 (1954).
Google Scholar
Jin, S. et al. Solid–solution-based metal alloy phase for highly reversible lithium metal anode. J. Am. Chem. Soc. 142, 8818–8826 (2020).
Google Scholar
Zhang, S. et al. Phase diagram determined lithium plating/stripping behaviors on lithiophilic substrates. ACS Energy Lett. 6, 4118–4126 (2021).
Google Scholar
Pecharromán, C. & Moya, J. S. Experimental evidence of a giant capacitance in insulator–conductor composites at the percolation threshold. Adv. Mater. 12, 294–297 (2000).
Google Scholar
Qi, L., Lee, B. I., Chen, S., Samuels, W. D. & Exarhos, G. J. High-dielectric-constant silver–epoxy composites as embedded dielectrics. Adv. Mater. 17, 1777–1781 (2005).
Google Scholar
Krylova, V. & Dukštienė, N. Synthesis and characterization of Ag2S layers formed on polypropylene. J. Chem. 2013, 987879 (2013).
Google Scholar
Wolan, J. T. & Hoflund, G. B. Surface characterization study of AgF and AgF2 powders using XPS and ISS. Appl. Surf. Sci. 125, 251–258 (1998).
Google Scholar
Shi, X. et al. Room-temperature ductile inorganic semiconductor. Nat. Mater. 17, 421–426 (2018).
Google Scholar
Guo, Z. et al. Combining solid solution strengthening and second phase strengthening for thinning Li metal foils. ACS Nano 17, 14136–14143 (2023).
Google Scholar
Zhang, S. et al. The lasting impact of formation cycling on the Li-ion kinetics between SEI and the Li-metal anode and its correlation with efficiency. Sci. Adv. 10, eadj8889 (2024).
Google Scholar
Huang, H. et al. Bonded interface enabled durable solid-state lithium metal batteries with ultra-low interfacial resistance of 0.25 Ω cm2. Adv. Funct. Mater. 34, 2407619 (2024).
Zhang, X. et al. Self-suppression of lithium dendrite in all-solid-state lithium metal batteries with poly(vinylidene difluoride)-based solid electrolytes. Adv. Mater. 31, 1806082 (2019).
Google Scholar
Deng, T. et al. In situ formation of polymer-inorganic solid-electrolyte interphase for stable polymeric solid-state lithium-metal batteries. Chem 7, 3052–3068 (2021).
Google Scholar
Hu, C. et al. Superionic conductors via bulk interfacial conduction. J. Am. Chem. Soc. 142, 18035–18041 (2020).
Google Scholar
Ma, Y. et al. Scalable, ultrathin, and high-temperature-resistant solid polymer electrolytes for energy-dense lithium metal batteries. Adv. Energy Mater. 12, 2103720 (2022).
Google Scholar
Wang, Z. et al. Lithium anode interlayer design for all-solid-state lithium-metal batteries. Nat. Energy 9, 251–262 (2024).
Google Scholar
Han, X. et al. Negating interfacial impedance in garnet-based solid-state Li metal batteries. Nat. Mater. 16, 572–579 (2016).
Google Scholar
Chen, B. et al. Achieving the high capacity and high stability of Li-rich oxide cathode in garnet-based solid-state battery. Angew. Chem. Int. Ed. 63, e202315856 (2023).
Google Scholar
Huo, H. et al. A flexible electron-blocking interfacial shield for dendrite-free solid lithium metal batteries. Nat. Commun. 12, 176 (2021).
Google Scholar
Ni, Y., Huang, C., Liu, H., Liang, Y. & Fan, L. Z. A high air-stability and Li-metal-compatible Li3+2xP1−xBixS4−1.5xO1.5x sulfide electrolyte for all-solid-state Li-metal batteries. Adv. Funct. Mater. 32, 2205998 (2022).
Google Scholar
Zeng, D. et al. Promoting favorable interfacial properties in lithium-based batteries using chlorine-rich sulfide inorganic solid-state electrolytes. Nat. Commun. 13, 1909 (2022).
Google Scholar
Ye, L. & Li, X. A dynamic stability design strategy for lithium metal solid state batteries. Nature 593, 218–222 (2021).
Google Scholar
Fan, X. et al. Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery. Sci. Adv. 4, 2375–7548 (2018).
Google Scholar
Wang, C. et al. A universal wet-chemistry synthesis of solid-state halide electrolytes for all-solid-state lithium-metal batteries. Sci. Adv. 7, eabh1896 (2021).
Google Scholar
Li, S. et al. Manipulation of charge transfer in vertically aligned epitaxial ferroelectric KNbO3 nanowire array photoelectrodes. Nano Energy 35, 92–100 (2017).
Google Scholar
Yao, Y. X. et al. Regulating interfacial chemistry in lithium-ion batteries by a weakly solvating electrolyte. Angew. Chem. Int. Ed. 60, 4090–4097 (2020).
Google Scholar
Pecharromán, C., Esteban-Betegón, F., Bartolomé, J. F., López-Esteban, S. & Moya, J. S. New percolative BaTiO3–Ni composites with a high and frequency-independent dielectric constant (εr≈80000). Adv. Mater. 13, 1541–1544 (2001).
Google Scholar
Ding, J. F. et al. Non-solvating and low-dielectricity cosolvent for anion-derived solid electrolyte interphases in lithium metal batteries. Angew. Chem. Int. Ed. 60, 11442–11447 (2021).
Google Scholar
Shi, P. et al. A dielectric electrolyte composite with high lithium-ion conductivity for high-voltage solid-state lithium metal batteries. Nat. Nanotechnol. 18, 602–610 (2023).
Google Scholar
Medlin, D. L., Yang, N., Spataru, C. D., Hale, L. M. & Mishin, Y. Unraveling the dislocation core structure at a van der Waals gap in bismuth telluride. Nat. Commun. 10, 1820 (2019).
Google Scholar
Xie, Y., Shibata, K. & Mizoguchi, T. A brute-force code searching for cell of non-identical displacement for CSL grain boundaries and interfaces. Comput. Phys. Commun. 273, 108260 (2022).
Google Scholar
Xie, Y. et al. InterOptimus: an AI-assisted robust workflow for screening ground-state heterogeneous interface structures in lithium batteries. J. Energy Chem. 106, 631–641 (2025).
Google Scholar
■ مصدر الخبر الأصلي
نشر لأول مرة على: www.nature.com
تاريخ النشر: 2025-10-29 02:00:00
الكاتب: Jinshuo Mi
تنويه من موقع “yalebnan.org”:
تم جلب هذا المحتوى بشكل آلي من المصدر:
www.nature.com
بتاريخ: 2025-10-29 02:00:00.
الآراء والمعلومات الواردة في هذا المقال لا تعبر بالضرورة عن رأي موقع “yalebnan.org”، والمسؤولية الكاملة تقع على عاتق المصدر الأصلي.
ملاحظة: قد يتم استخدام الترجمة الآلية في بعض الأحيان لتوفير هذا المحتوى.
